Chemistry 9701 · AS & A Level · Nitrogen compounds

Nitrogen compounds — practice question

When gaseous ammonia meets gaseous hydrogen chloride, solid ammonium chloride is formed. The bonding in ammonium chloride involves ionic, covalent and co-ordinate (dative covalent) bonds.
(a)[3]

Complete the dot-and-cross diagram below to show the bonding in ammonium chloride. Show all the outer-shell electrons for each of the six atoms. Three electrons have already been drawn. Use this code for the electrons: electrons from chlorine, electrons from hydrogen, electrons from nitrogen.

(b(i))[1]

Suggest why concentrated $\text{H}_2\text{SO}_4$, the standard drying agent for gases, is not used to dry ammonia.

(b(ii))[1]

Write an equation for the reaction of $\text{CaO}$ with $\text{H}_2\text{O}$.

(b(iii))[1]

Suggest why $\text{CaO}$ is used instead of $\text{MgO}$ to dry ammonia.

(c(i))[2]

Write an equation showing the thermal decomposition of calcium nitrate, $\text{Ca(NO}_3)_2$.

(c(ii))[2]

State and explain how the thermal stabilities of the nitrates change down Group II.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: The chlorine atom has $8e^-$ in its outer shell

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI