Chemistry 9701 · AS & A Level · Nitrogen compounds

Nitrogen compounds — practice question

Mohr’s salt is a pale green crystalline solid that dissolves in water. It contains two cations, one of which is $\text{Fe}^{2+}$, and one anion, which is $\text{SO}_4^{2-}$. The second cation was identified by heating solid Mohr’s salt with solid sodium hydroxide, when a colourless gas was given off. This gas dissolved easily in water to produce an alkaline solution. A grey-green solid residue was also produced, and this residue did not dissolve in water. What are the identities of the gas and the solid residue?

  • Agas: $\text{NH}_3$, residue: $\text{Fe(OH)}_2$
  • Bgas: $\text{NH}_3$, residue: $\text{Na}_2\text{SO}_4$
  • Cgas: $\text{SO}_2$, residue: $\text{Fe(OH)}_2$
  • Dgas: $\text{SO}_2$, residue: $\text{Na}_2\text{SO}_4$

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