Chemistry 9701 · AS & A Level · Nitrogen compounds

Nitrogen compounds — practice question

2-aminobutane, $\text{CH}_3\text{CH(NH}_2)\text{CH}_2\text{CH}_3$, is found as a mixture of two enantiomers.
(a)[1]

Define enantiomers in chemistry.

(b(i))[2]

Explain why a water solution of 2-aminobutane has a pH greater than 7. Include an equation in your response.

(b(ii))[2]

A $0.10\,\text{mol dm}^{-3}$ solution of diethylamine, $(\text{CH}_3\text{CH}_2)_2\text{NH}$, has a higher pH than a $0.10\,\text{mol dm}^{-3}$ solution of 2-aminobutane, $\text{CH}_3\text{CH(NH}_2)\text{CH}_2\text{CH}_3$. Suggest why.

(b(iii))[1]

$(\text{CH}_3\text{CH}_2)_2\text{NH}$ reacts with ethanoic acid, $\text{CH}_3\text{COOH}$. Complete the equation for this reaction: $(\text{CH}_3\text{CH}_2)_2\text{NH} + \text{CH}_3\text{COOH} \rightarrow \ldots$

(b(iv))[1]

$(\text{CH}_3\text{CH}_2)_2\text{NH}$ reacts with ethanoyl chloride, $\text{CH}_3\text{COCl}$. Complete the equation for this reaction: $(\text{CH}_3\text{CH}_2)_2\text{NH} + \text{CH}_3\text{COCl} \rightarrow \ldots$

(c(i))[1]

Table 7.1 lists monomers that can undergo polymerisation. Complete Table 7.1.

(c(ii))[2]

Ethanedioic acid, $\text{HOOC-COOH}$, can react with propane-1,3-diamine, $\text{H}_2\text{NCH}_2\text{CH}_2\text{CH}_2\text{NH}_2$, to make polymer W. Draw one repeat unit of polymer W, showing only a single repeat unit. The new functional group formed should be displayed.

(c(iii))[1]

Poly(alkenes) biodegrade very slowly. Explain why.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: An equal-sized rotation in the opposite sense

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI