Chemistry 9701 · AS & A Level · Nitrogen compounds

Nitrogen compounds — practice question

Asparagine and valine are both amino acids that occur naturally.
(a)[1]

Give the molecular formula for asparagine.

(b)[2]

Name every functional group present in an asparagine molecule.

(c)[2]

Draw the structure of the dipeptide made from valine and asparagine. The peptide bond should be displayed and clearly labelled.

(d(i))[2]

Explain what is meant by a buffer solution.

(d(ii))[2]

Write two equations to show how valine can work as a buffer. Use the formula $\text{H}_2\text{NCHRCO}_2\text{H}$ for valine in your equations.

(e)[2]

Each valine molecule contains one chiral carbon atom. Draw three-dimensional diagrams to show the two optical isomers of valine. The $(\text{CH}_3)_2\text{CH}$ group may be shown as R.

(f)[2]

Asparagine is hydrolysed on heating with aqueous sulfuric acid. Write an equation for this reaction.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: $\mathrm{C_4H_8N_2O_3}$

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