Chemistry 5070 · O Level · The characteristic properties of acids and bases

The characteristic properties of acids and bases — practice question

Hydrochloric acid, $\text{HCl}$, is neutralised as it is added to aqueous potassium hydroxide, $\text{KOH}$. $\text{KOH} + \text{HCl} \rightarrow \text{KCl} + \text{H}_2\text{O}$ The reaction gives out heat. $\textbf{P}$ is aqueous potassium hydroxide. $\textbf{Q}$ is $2.24\ \text{mol}/\text{dm}^3$ hydrochloric acid. A student finds the concentration of potassium hydroxide in $\textbf{P}$. The student carries out six experiments. The student: Step 1. uses a volumetric pipette to place $25.0\ \text{cm}^3$ of $\textbf{P}$ into a plastic cup Step 2. uses a measuring cylinder to add $20\ \text{cm}^3$ of distilled water to the plastic cup Step 3. stirs the mixture in the cup with a thermometer and notes its temperature to the nearest $0.5\ ^\circ\text{C}$ Step 4. uses a burette to add $5.0\ \text{cm}^3$ of $\textbf{Q}$ to the plastic cup and stirs Step 5. records the greatest temperature reached Step 6. empties the plastic cup and washes it out with water Step 7. repeats steps $1$-$6$ using five other volumes of distilled water and $\textbf{Q}$ so that the total volume in the cup is always $50\ \text{cm}^3$. The student’s results are given in Table 2.1.
(a)[3]

Use Table 2.1 to complete the three missing entries.

(b)[1]

The parts of the thermometer used in Experiment $5$ are shown in Fig. 2.1. The liquid levels inside the thermometer are not shown. Finish Fig. 2.1 by drawing the liquid level to represent: • the initial temperature of $\textbf{P}$ in Experiment $5$ • the highest temperature reached in Experiment $5$.

(c)[3]

Draw a graph of temperature rise against volume of $\textbf{Q}$ on the grid in Fig. 2.2. You should: • plot the point $(0,0)$ because there is no temperature rise when no $\textbf{Q}$ is added • plot the temperature rises and volumes of $\textbf{Q}$ from Table 2.1 • draw a straight line of best fit for the first four points • draw a straight line of best fit for the last three points • extend the lines so that they intersect.

(d)[1]

The point where the two lines meet shows the volume of $\textbf{Q}$ that exactly neutralises $25.0\ \text{cm}^3$ of $\textbf{P}$. Determine the volume of $\textbf{Q}$ at the point where the two lines on the graph cross.

(e)[2]

$\textbf{Q}$ is $2.24\ \text{mol}/\text{dm}^3$ hydrochloric acid. Use your answer to (d) to calculate the concentration of potassium hydroxide in $\textbf{P}$. $\text{KOH} + \text{HCl} \rightarrow \text{KCl} + \text{H}_2\text{O}$

(f)[1]

A measuring cylinder is used to measure the volumes of water. Suggest why the volumes of water in Table 2.1 are not shown to one decimal place.

(g)[2]

State and explain why a plastic cup is used instead of a metal cup in these experiments.

(h)[1]

State why the mixture is stirred before the temperature is measured in these experiments.

Worked solution & mark scheme

This 14-mark question has a full step-by-step worked solution and mark scheme. One marking point: M1 = 15 cm^3

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI