Chemistry 5070 · O Level · Rate of reaction

Rate of reaction — practice question

A student places large pieces of zinc into dilute hydrochloric acid, with the zinc present in excess.
(a)[1]

Complete the equation by inserting state symbols for the products: $\text{Zn}(s)+2\text{HCl}(aq)\rightarrow\text{ZnCl}_2(\ )+\text{H}_2(\ )$.

(b(i))[1]

Describe how the graph in Fig. 5.1 indicates that the rate of reaction falls with time.

(b(ii))[2]

Explain in terms of collision theory why the rate of reaction falls with time.

(b(iii))[2]

Describe and explain the change in reaction rate when powdered zinc is used.

(c)[3]

Calculate the volume of hydrogen gas produced at room temperature and pressure when excess zinc reacts with $16.0\text{ cm}^3$ of $0.400\text{ mol dm}^{-3}$ hydrochloric acid. Give your answer to two significant figures.

(d)[3]

Complete the reaction pathway diagram in Fig. 5.2 so that it shows the reactants and products, a labelled arrow for the activation energy $E_a$, and a labelled arrow for the enthalpy change $\Delta H$.

(e)[2]

Describe the observations seen when a few drops of aqueous ammonia are added, and when excess aqueous ammonia is added, to an aqueous solution containing zinc ions.

(f)[3]

Describe how pure, dry zinc chloride crystals are prepared after excess zinc has reacted with dilute hydrochloric acid.

Worked solution & mark scheme

This 17-mark question has a full step-by-step worked solution and mark scheme. One marking point: Answer: ZnCl₂(aq) + H₂(g)

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