Chemistry 5070 · O Level · Identification of ions and gases

Identification of ions and gases — practice question

A student carries out a sequence of experiments to examine solution R.
(a(i))[2]

The student leaves one end of a wooden splint dipped in R for ten minutes. The damp end of the splint is then put into a blue Bunsen burner flame.\n\nThe flame first shows a red colour briefly and then becomes yellow.\n\nState two possible conclusions from this observation.

(a(ii))[1]

Explain why the observation in (a)(i) does not allow a definite conclusion.

(b)[1]

The student first adds dilute nitric acid to R, then adds aqueous barium nitrate.\n\nThe student decides that R does not contain sulfate ions.\n\nState the observation that lets the student reach this conclusion.

(c)[1]

The student adds dilute nitric acid to R, then adds aqueous silver nitrate.\n\nA white precipitate is seen.\n\nState a conclusion from this observation.

(d(i))[1]

The student adds aqueous silver nitrate to aqueous sodium carbonate, and a white precipitate appears.\n\nThe student then adds dilute nitric acid drop by drop until there is no further change.\n\nThe white precipitate dissolves and a colourless solution is produced.\n\nDescribe one other observation.

(d(ii))[1]

Suggest why dilute nitric acid is added in (c).

(e)[1]

The student adds a few drops of aqueous sodium hydroxide to R.\n\nState the observation that suggests R may contain $\text{Ca}^{2+}$.

(f)[2]

Describe what else the student must do to confirm the presence of $\text{Ca}^{2+}$ ions.\n\nState what the student sees.

(g(i))[1]

The student warms the solution from (e).\n\nThe student concludes that ammonia gas is produced.\n\nState the observation that confirms ammonia gas is produced.

(g(ii))[1]

Identify a cation present in R other than calcium.

(h)[2]

Solution R is prepared from a mixture of two different ionic compounds.\n\nSuggest the names of these two compounds.

Worked solution & mark scheme

This 14-mark question has a full step-by-step worked solution and mark scheme. One marking point: Li+ ions / lithium ions

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