Chemistry 5070 · O Level · Giant covalent structures

Giant covalent structures — practice question

Silicon is classified as a non-metal in Group IV of the Periodic Table.
(a)[2]

Silicon is obtained by reducing silicon dioxide with carbon. $\text{SiO}_2 + 2\text{C} \rightarrow \text{Si} + 2\text{CO}$. What is the greatest mass of silicon that can be produced from $300\,\text{g}$ of silicon dioxide?

(b)[2]

Silicon has a giant molecular structure. Suggest any two physical properties of silicon.

(c(i))[1]

Draw the dot-and-cross diagram for silane, $\text{SiH}_4$. Show only the outer shell electrons of silicon.

(c(ii))[2]

Using ideas about structure and bonding, suggest why silane has a low boiling point.

(d(i))[2]

What is meant by condensation polymerisation?

(d(ii))[1]

Draw the repeat unit for this siloxane.

(e)[1]

Butene undergoes addition polymerisation to make poly(butene). Draw part of the structure of poly(butene). You must include at least two repeat units.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: n(SiO₂) = 5, therefore percentage of Si in SiO₂ = 46.67

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