Chemistry 5070 · O Level · Acid–base titrations

Acid–base titrations — practice question

When dilute nitric acid reacts with aqueous barium hydroxide: $2\text{HNO}_3(aq) + \text{Ba(OH)}_2(aq) \rightarrow \text{Ba(NO}_3)_2(aq) + 2\text{H}_2\text{O}(l)$
(a(i))[3]

A student carries out a titration of 25.0 cm$^3$ of dilute nitric acid with 0.0450 mol/dm$^3$ barium hydroxide, using methyl orange as the indicator. Exactly 34.0 cm$^3$ of aqueous barium hydroxide neutralises the dilute nitric acid. Calculate the concentration of the dilute nitric acid.

(a(ii))[3]

Describe how to obtain pure dry crystals of barium nitrate from aqueous barium nitrate.

(b)[1]

On heating, barium nitrate breaks down to make barium oxide, BaO, nitrogen dioxide, NO$_2$, and oxygen. Construct the equation for this reaction.

(c)[1]

Nitrogen dioxide is an atmospheric pollutant that leads to ‘acid rain’. Describe one effect of acid rain on buildings.

(d(i))[1]

Hydrazine, H$_2$N-NH$_2$, is a colourless liquid. Draw a dot-and-cross diagram for one molecule of hydrazine. Show only the outer-shell electrons.

(d(ii))[1]

The melting point of hydrazine is 2 ^{\circ}C. The boiling point of hydrazine is 114 ^{\circ}C. Use these facts to suggest why hydrazine is a solid at 0 ^{\circ}C.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: Calculate: moles Ba(OH)₂ = 0.045 \times 34.0/1000

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