Chemistry 0620 · IGCSE · Reversible reactions and equilibrium

Reversible reactions and equilibrium — practice question

Gaseous sulfur tetrafluoride, $\mathrm{SF_4}$, undergoes a reversible reaction with steam. $\mathrm{SF_4(g)+2H_2O(g)\rightleftharpoons SO_2(g)+4HF(g)}$ $\Delta H=-54\text{ kJ/mol}$
(a)[4]

Complete the reaction pathway diagram in Fig. 4.1 for this reaction. Your diagram should show: the position and the formulae of the products; an arrow, labelled $E_a$, to indicate the activation energy; an arrow, labelled $\Delta H$, to indicate the enthalpy change of the reaction.

(b)[4]

Calculate the bond energy of S=O in kJ/mol.

(c)[5]

State the effect, if any, on the equilibrium position when each of the changes below is made. Give a reason for every answer. The temperature is increased. The pressure is increased. A catalyst is added.

(d)[3]

Explain, in terms of collision theory, why a decrease in temperature lowers the rate of the reverse reaction.

Worked solution & mark scheme

This 16-mark question has a full step-by-step worked solution and mark scheme. One marking point: M1 product energy level below reactant energy level

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