Chemistry 0620 · IGCSE · Reversible reactions and equilibrium

Reversible reactions and equilibrium — practice question

Dinitrogen tetroxide, N₂O₄, breaks down to nitrogen dioxide, NO₂. This is a reversible reaction. $\text{N}_2\text{O}_4(g) \rightleftharpoons 2\text{NO}_2(g)$ Fig. 4.1 shows a sealed gas syringe that contains a mixture of dinitrogen tetroxide and nitrogen dioxide. The gas syringe is sealed. The mixture reaches equilibrium and the gases are a pale brown.
(a)[2]

Describe a reversible reaction at equilibrium by referring to the forward and reverse reaction rates and the concentrations of the reactants and products.

(b)[1]

Explain in particle terms why the mixture immediately becomes a darker brown.

(c)[1]

State what can be deduced about the forward reaction from this information.

(d(i))[4]

Complete Table 4.1 using only the words increases, decreases or no change.

(d(ii))[2]

Deduce the oxidation number of sulfur in S and in SO₃.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: Forward and backward reaction rates are the same

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