Chemistry 0620 · IGCSE · Reversible reactions and equilibrium

Reversible reactions and equilibrium — practice question

Dinitrogen tetroxide, N$_2$O$_4$, breaks down to form nitrogen dioxide, NO$_2$. This reaction can go in both directions. $\text{N}_2\text{O}_4(g) \rightleftharpoons 2\text{NO}_2(g)$ (colourless gas ⇌ brown gas). A gas syringe holding a mixture of dinitrogen tetroxide and nitrogen dioxide gases was sealed and then heated. Once equilibrium was reached, the mixture had a pale brown colour.
(a)[2]

State the meaning of the term equilibrium.

(b(i))[1]

Explain why the mixture first turns a darker brown.

(b(ii))[1]

Explain why equilibrium moves to the left.

(c(i))[1]

State how the position of equilibrium changes when the temperature of the mixture is increased.

(c(ii))[2]

State how the rate of the forward reaction and the rate of the backward reaction change when the temperature of the mixture is increased.

Worked solution & mark scheme

This 7-mark question has a full step-by-step worked solution and mark scheme. One marking point: forward reaction rate is equal to reverse reaction rate

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