Physics 9702 · AS & A Level · The first law of thermodynamics

The first law of thermodynamics — practice question

A cylinder holds a fixed mass of an ideal gas at pressure $2Y$ and volume $6X$. The gas is taken through a series of changes from its starting state A, via states B, C and D, and then returns to its starting state A, as shown in Fig. 4.1. Fig. 4.2 displays how the internal energy of the gas varies with time.
(a)[2]

State the first law of thermodynamics in words or as an equation.

(b(i))[1]

Using Fig. 4.1 and Fig. 4.2, find the general expression for the internal energy $U$ of the gas when its pressure is $p$ and its volume is $V$.

(b(ii))[2]

An ideal gas at thermodynamic temperature $T$ contains $N$ molecules. Using your answer in (b)(i) and the equation of state for an ideal gas, deduce an expression for $U$ in terms of $N$ and $T$. Identify any other symbols you use.

(c(i))[1]

Find expressions, in terms of $X$ and $Y$, for the work $W$ done on the gas during change AB.

(c(ii))[1]

Find expressions, in terms of $X$ and $Y$, for the work $W$ done on the gas during change CD.

(d)[3]

Using your answers in (c) and the first law of thermodynamics, determine an expression, in terms of $X$ and $Y$, for the net thermal energy $Q$ supplied to the gas in one complete cycle ABCDA. Explain your reasoning.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: change in internal energy = work done + energy transfer by heating

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