Physics 9702 · AS & A Level · Kinetic theory of gases

Kinetic theory of gases — practice question

(a)[2]

Define the meaning of specific heat capacity.

(b)

A sealed container with fixed volume $V$ holds an ideal gas at pressure $p$, containing $N$ molecules, each of mass $m$.

(b(i))[1]

State an expression, in terms of $V$, $N$, $p$ and the Boltzmann constant $k$, for the thermodynamic temperature $T$ of the gas.

(b(ii))[2]

Show that the mean translational kinetic energy $E_K$ of a molecule of the gas is given by $E_K = \frac{3}{2}kT$.

(b(iii))[2]

Explain why the internal energy of the gas is equal to the total kinetic energy of the molecules.

(c(i))[2]

The gas in (b) receives thermal energy $Q$. Explain, with reference to the first law of thermodynamics, why the increase in internal energy of the gas is $Q$.

(c(ii))[2]

Use the expression in (b)(ii) together with the information in (c)(i) to show that the specific heat capacity $c$ of the gas is given by $c = \frac{3k}{2m}$.

(d)[2]

The container in (b) is now replaced by one without a fixed volume. Instead, the gas is allowed to expand, so that the pressure of the gas stays constant as thermal energy is supplied. Suggest, with a reason, how the specific heat capacity of the gas would now compare with the value in (c)(ii).

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: thermal energy needed per unit mass (to produce a temperature change)

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