Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

The elements in Group 14 change from non-metallic to metallic in character as you move down the group.
(a(i))[3]

Complete Table 3.1 by filling in the missing entries.

(a(ii))[1]

Identify the lattice structure shown by graphite.

(a(iii))[1]

Explain why Sn has good electrical conductivity.

(b(i))[1]

Write an equation for the reaction of magnesium carbonate with dilute $\text{HCl(aq)}$.

(b(ii))[1]

Describe the thermal stability of the carbonates down Group 2.

(b(iii))[2]

Ammonium carbonate undergoes an acid-base reaction with $\text{NaOH(aq)}$.\n\nExplain this statement.

(c(i))[2]

Complete the graph in Fig. 3.1 to show the third to sixth ionisation energies of Si.

(c(ii))[1]

Construct an equation to represent the second ionisation energy of Si.

(d(i))[2]

Explain the trend in the boiling points of the Group 14 hydrides shown in Fig. 3.2.

(d(ii))[1]

Deduce the shape of a molecule of $\text{SiH}_4$.

(e(i))[1]

Write an equation for the formation of $\text{SiCl}_4$ from its constituent elements.

(e(ii))[1]

Describe what is observed when a small sample of $\text{SiCl}_4$ is added to water.

(e(iii))[2]

$\text{SiO}_2$ is a white solid that melts above $1700^\circ\text{C}$. $\text{SiCl}_4$ is a colourless liquid at room temperature. Explain the difference in the melting points of these two compounds with reference to their structure and bonding.

(f)[1]

Tin forms an amphoteric oxide, $\text{SnO}_2$. Suggest the formula of the tin compound that forms when $\text{SnO}_2$ reacts with $\text{H}_2\text{SO}_4$ in an acid-base reaction.

Worked solution & mark scheme

This 20-mark question has a full step-by-step worked solution and mark scheme. One marking point: Graphite: grey, shiny solid, good conductor, covalent bonding, giant structure

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