Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

Cobalt, rhodium and iridium are metals that belong to the same group in the Periodic Table.
(a(i))[1]

The shorthand electronic configuration of cobalt is $[\text{Ar}]3d^74s^2$. Identify what $[\text{Ar}]$ means by giving the full electronic configuration.

(a(ii))[1]

The electrons with the lowest energy in cobalt occupy the $1s$ orbital. Sketch the form of a $1s$ orbital.

(a(iii))[1]

Deduce how many unpaired electrons are present in a cobalt atom.

(b)[3]

Table 1.1 provides details of the stable naturally occurring isotopes of rhodium and iridium. Complete Table 1.1.

(c(i))[2]

Define relative isotopic mass.

(c(ii))[2]

Use Table 1.2 to calculate the relative atomic mass, $A_r$, of iridium in the alloy. Give your answer to two decimal places.

(d(i))[2]

Hydrated rhodium(III) chloride, $\text{RhCl}_3\cdot x\text{H}_2\text{O}$, has $20.5\%$ by mass of water of crystallisation. Deduce the integer value of $x$ in $\text{RhCl}_3\cdot x\text{H}_2\text{O}$. Show your working.

(d(ii))[1]

Define stereoisomers.

(d(iii))[1]

Explain how the conversion of ethene to but-2-ene can be described as an addition reaction.

(d(iv))[2]

Draw the two stereoisomers of but-2-ene.

Worked solution & mark scheme

This 16-mark question has a full step-by-step worked solution and mark scheme. One marking point: Full electronic configuration: $1s^2 2s^2 2p^6 3s^2 3p^6$

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