Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

Oxygen belongs to Group 16.
(a(i))[2]

Write equations for these reactions: sodium with oxygen; sulfur with oxygen.

(a(ii))[1]

Draw a dot-and-cross diagram to show the species present in $\text{Al}_2\text{O}_3$. Show only outer electrons.

(a(iii))[2]

The maximum oxidation state of the Period 3 elements in their oxides changes across the period. State and explain the pattern.

(b(i))[2]

Complete Table 2.1 with details of how some Period 3 oxides react with $\text{H}_2\text{O}$.

(b(ii))[1]

Write an equation for the reaction of $\text{CH}_3\text{CN}$ with $\text{H}_2\text{O}$ under acidic conditions. $\text{CH}_3\text{CN} + \ldots\,\text{H}_2\text{O} + \ldots\,\text{H}^+ \rightarrow \ldots$

(b(iii))[2]

Draw the structures of the two alcohols produced in equation 1. Equation 1: $\text{C}_3\text{H}_6(g) + \text{H}_2\text{O}(g) \xrightarrow{\text{H}_3\text{PO}_4} \text{C}_3\text{H}_8\text{O}(g)$

(b(iv))[2]

Explain why alcohols are less acidic than water.

(c(i))[2]

Explain the trend in the boiling points of the Group 16 hydrides from $\text{H}_2\text{S}$ to $\text{H}_2\text{Te}$.

(c(ii))[1]

Explain why the boiling point of $\text{H}_2\text{O}$ is much higher than the boiling point of $\text{H}_2\text{S}$.

Worked solution & mark scheme

This 15-mark question has a full step-by-step worked solution and mark scheme. One marking point: $4\mathrm{Na} + \mathrm{O}_2 \rightarrow 2\mathrm{Na}_2\mathrm{O}$

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