Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

The oxides of Period 3 shown here are listed with their boiling points and the type of oxide they are.
(a)[2]

Fill in the table with the bonding type and structure for some Period 3 oxides.

(b(i))[3]

Explain why the boiling point of $\text{SiO}_2$ is much higher than that of $\text{SO}_3$.

(b(ii))[3]

Explain what the term amphoteric means for $\text{Al}_2\text{O}_3$. Use chemical equations to illustrate your answer.

(b(iii))[1]

State what you would observe when a small piece of $\text{Na}_2\text{O}$ is put into water.

(c(i))[1]

Selenium reacts with fluorine to produce $\text{SeF}_6$ molecules. Predict the shape of a molecule of $\text{SeF}_6$.

(c(ii))[2]

Gaseous $\text{SeO}_2$ reacts to make a solid polymer, as shown. In this reaction, one Se=O bond is replaced by two Se-O bonds to form a polymer. The bond enthalpy of Se=O is $514\ \text{kJ mol}^{-1}$. Use these data to calculate the bond enthalpy, in $\text{kJ mol}^{-1}$, of Se-O.

(c(iii))[1]

Because $\text{SeO}_2$ reacts in a similar way to $\text{SO}_2$, suggest an equation showing how $\text{SeO}_2$ reacts with aqueous sodium hydroxide, $\text{NaOH}$.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: These oxides, $\mathrm{Na_2O, MgO, Al_2O_3}$, are ionic and giant

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