Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

Several oxides of Period 3 elements are displayed, namely $\text{Na}_2\text{O}$, $\text{MgO}$, $\text{Al}_2\text{O}_3$, $\text{SiO}_2$ and $\text{SO}_3$, together with the stated boiling points and oxide type.
(a)[2]

Fill in the table with the bonding type and structural type shown by some Period 3 oxides.

(b(i))[3]

Explain why the boiling point of $\text{SiO}_2$ is much higher than that of $\text{SO}_3$.

(b(ii))[3]

$\text{Al}_2\text{O}_3$ is an amphoteric oxide. Explain what is meant by amphoteric. Use chemical equations to support your answer.

(b(iii))[1]

State what you would observe when a small amount of $\text{Na}_2\text{O}$ is added to water.

(c(i))[1]

Selenium reacts with fluorine to form $\text{SeF}_6$ molecules. Predict the shape of a $\text{SeF}_6$ molecule.

(c(ii))[2]

The most stable oxide of selenium is $\text{SeO}_2$. Gaseous $\text{SeO}_2$ changes to form a solid polymer, as shown. In the reaction, one $\text{Se}=\text{O}$ is replaced by two $\text{Se}-\text{O}$ to make a polymer. The bond enthalpy of $\text{Se}=\text{O}$ is $514\,\text{kJ mol}^{-1}$. Use these data to work out the bond enthalpy, in $\text{kJ mol}^{-1}$, of $\text{Se}-\text{O}$. ($\Delta H = -346\,\text{kJ mol}^{-1}$)

(c(iii))[1]

$\text{SeO}_2$ shows chemical reactions similar to $\text{SO}_2$. Suggest an equation to show how $\text{SeO}_2$ reacts with aqueous sodium hydroxide, $\text{NaOH}$.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: $\mathrm{Na_2O, MgO, Al_2O_3}$ are ionic and have giant structures

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