Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

(a)[1]

Construct an equation that represents the second ionisation energy of argon.

(b)[2]

The graph plots successive ionisation energies for argon. Extend the graph by predicting the eighth and ninth ionisation energies of argon. Mark each point with a cross ($\times$).

(c)[1]

The energy value needed to remove the first electron from an argon atom has been circled on the graph. Sketch the shape of the orbital that contains this electron.

(d(i))[3]

Chlorine is a diatomic gas, $\text{Cl}_2(\text{g})$. A sample of $\text{Cl}_2(\text{g})$ was produced in a chemical reaction. It had a volume of $20.0\,\text{cm}^3$ when measured at $404\,\text{kPa}$ and $25\,^{\circ}\text{C}$. Calculate the mass, in grams, of $\text{Cl}_2(\text{g})$ produced. For this calculation, assume chlorine behaves as an ideal gas under these conditions.

(d(ii))[2]

Calculate how many chlorine atoms are present in this sample of $\text{Cl}_2(\text{g})$. You may want to use your answer to (d)(i). If you cannot work out an answer to (d)(i), use $0.36\,\text{g}$ of $\text{Cl}_2$. This is not the correct answer.

(d(iii))[2]

$\text{Cl}_2(\text{g})$ is not an ideal gas under these conditions. Explain why $\text{Cl}_2(\text{g})$ becomes even less ideal at: • very high pressures • very low temperatures.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: either $\mathrm{Ar^+(g) \rightarrow Ar^{2+}(g) + e^-}$ or $\mathrm{Ar^+(g) - e^- \rightarrow Ar^{2+}(g)}$

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