Chemistry 9701 · AS & A Level · The Periodic Table: chemical periodicity

The Periodic Table: chemical periodicity — practice question

(a)[3]

Explain the meaning of ionisation energy.

(b)

The first seven ionisation energies for an element, $A$, in $\text{kJ mol}^{-1}$, are: $1012$, $1903$, $2912$, $4957$, $6274$, $21269$, $25398$.

(b(i))[2]

State which group of the Periodic Table $A$ is most likely in. Justify your response.

(b(ii))[1]

Give the full electronic configuration of the Period 2 element in the same group as $A$. $1s^2$ \dotfill

(c)

A different element, $Z$, from the same group of the Periodic Table as $A$, reacts with chlorine to make a compound whose empirical formula is $ZCl_2$. The percentage composition by mass of $ZCl_2$ is: $Z$, $31.13$; $Cl$, $68.87$.

(c(i))[2]

Define relative atomic mass.

(c(ii))[2]

Calculate the relative atomic mass, $A_r$, of $Z$. Give your answer to three significant figures.

(d)

Chlorides of the Period 3 elements in the Periodic Table behave differently when water is added, because their structures and bonding are not the same.

(d(i))[2]

Write equations to show what happens when sodium chloride, $NaCl$, and silicon chloride, $SiCl_4$, are each placed in excess water.

(d(ii))[4]

State and explain how these two chlorides differ in their behaviour when added to water, in terms of their structures and the bonding present.

(e)[2]

Sulfur reacts with fluorine to make $SF_6$. State the shape of $SF_6$ and its bond angle.

Worked solution & mark scheme

This 18-mark question has a full step-by-step worked solution and mark scheme. One marking point: Energy needed / energy change / enthalpy change when one electron is taken from each atom / cation in one mole of gaseous atoms / cations

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