Chemistry 9701 · AS & A Level · States of matter

States of matter — practice question

(a(i))[1]

The species $[\text{MnCl}_4]^{2-}$ is a complex ion. Deduce the oxidation state of manganese in $[\text{MnCl}_4]^{2-}$.

(a(ii))[2]

The $[\text{MnCl}_4]^{2-}$ complex does not include any $180^\circ$ bond angles. Produce a three-dimensional diagram to show the shape of the $[\text{MnCl}_4]^{2-}$ complex. State one bond angle on your diagram.

(b(i))[2]

A solution containing $[\text{Co(H}_2\text{O)}_6]^{2+}$ is treated with excess $\text{NaOH(aq)}$. Write an equation for this reaction. State one observation that can be made immediately after the reaction, including the colour and state of the cobalt-containing product.

(b(ii))[2]

A solution containing $[\text{Co(H}_2\text{O)}_6]^{2+}$ is treated with excess $\text{NH}_3\text{(aq)}$. Write an equation for this reaction. State one observation that can be made immediately after the reaction, including the colour and state of the cobalt-containing product.

(b(iii))[2]

A solution containing $[\text{Co(H}_2\text{O)}_6]^{2+}$ is treated with excess $\text{NaCl(aq)}$. Write an equation for this reaction. State one observation that can be made immediately after the reaction, including the colour and state of the cobalt-containing product.

(b(iv))[1]

Name the type of reaction that takes place in (b)(iii).

(c(i))[2]

The complex ion $[\text{Co(NH}_3\text{)}_2(\text{en})_2]^{2+}$ is formed by cobalt. The abbreviation $\text{en}$ is used for the bidentate ligand 1,2-diaminoethane, $\text{H}_2\text{NCH}_2\text{CH}_2\text{NH}_2$. Define the term bidentate ligand.

(c(ii))[2]

Draw three-dimensional diagrams of the two optical isomers of $[\text{Co(NH}_3\text{)}_2(\text{en})_2]^{2+}$. Each en ligand may be shown as N- -N.

(c)

Cobalt forms the complex ion $[\text{Co(NH}_3)_2(\text{en})_2]^{2+}$. The abbreviation en is used for the bidentate ligand 1,2-diaminoethane, $\text{H}_2\text{NCH}_2\text{CH}_2\text{NH}_2$. This complex ion exhibits both geometrical and optical isomerism.

Worked solution & mark scheme

This 14-mark question has a full step-by-step worked solution and mark scheme. One marking point: Oxidation state is $+2$

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