Chemistry 9701 · AS & A Level · States of matter

States of matter — practice question

It is possible to synthesise 3-aminobenzoic acid from methylbenzene in three steps.
(a(i))[2]

In the boxes, draw the structures of $ ext{M}$ and $ ext{N}$.

(a(ii))[3]

Suggest the reagents and reaction conditions for each stage of the synthesis.

(b(i))[3]

A mixture containing serine, $\text{HOCH}_2\text{CH(NH}_2)\text{CO}_2\text{H}$, and lysine, $\text{H}_2\text{N(CH}_2)_4\text{CH(NH}_2)\text{CO}_2\text{H}$, forms a range of different products. Draw the structures of the two structural isomers with molecular formula $\text{C}_6\text{H}_{12}\text{N}_2\text{O}_5$ that may be present in the product mixture. The functional group formed in each one should be shown.

(b(ii))[1]

Predict how many different structural isomers with molecular formula $\text{C}_9\text{H}_{19}\text{N}_3\text{O}_4$ could be present in the product mixture.

(c(i))[1]

Glutathione is a naturally occurring compound found in plants. On the glutathione diagram, mark each chiral centre with an asterisk $(*)$.

(c(ii))[2]

Draw the structures of the three products formed after complete acid hydrolysis of glutathione. Assume that the thiol group, $-\text{SH}$, does not react.

(c(iii))[1]

Glutathione is soluble in water. Using the structure of glutathione, explain why it dissolves in water.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate structures of M and N

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI