Chemistry 9701 · AS & A Level · States of matter

States of matter — practice question

(a)[3]

By referring to the formation of $\sigma$ and $\pi$ bonds, describe and explain the shape of a benzene molecule, $\text{C}_6\text{H}_6$.

(b(i))[1]

2,3-dimethylphenylamine can be made from 1,2-dimethylbenzene in two steps, as shown. Step 1 is catalysed by $\text{H}_2\text{SO}_4$. Write an equation to show how $\text{H}_2\text{SO}_4$ produces the electrophile in step 1.

(b(ii))[3]

Draw the mechanism for the reaction between this electrophile and 1,2-dimethylbenzene to form $M$. Include all relevant curly arrows and charges.

(b(iii))[1]

Write an equation to show how the $\text{H}_2\text{SO}_4$ catalyst is reformed.

(b(iv))[2]

For step 2, suggest the reagents and conditions and name the type of reaction.

(c(i))[1]

Deduce the molecular formula for mefenamic acid.

(c(ii))[1]

Name the functional groups, other than the benzene ring, in mefenamic acid.

(c(iii))[2]

Calculate the maximum mass of mefenamic acid that could be made from $5.00\,\text{g}$ of 2,3-dimethylphenylamine in this reaction. Give your answer to three significant figures.

(d)[2]

Use this information and your knowledge of cation stability to suggest why the $\text{CH}_3$ group directs incoming electrophiles to the 2- and 4-positions rather than the 3-position.

Worked solution & mark scheme

This 16-mark question has a full step-by-step worked solution and mark scheme. One marking point: Any three accurate points on benzene structure

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