Chemistry 9701 · AS & A Level · States of matter

States of matter — practice question

Two isomeric complexes exist with the formula $\text{Pt}(\text{NH}_3)_2\text{Cl}_2$, and one of them is used as an anti-cancer drug.
(a(i))[2]

Draw diagrams to illustrate the three-dimensional structures of the two isomers.

(a(ii))[1]

Comment on the polarity of the two isomers of $\text{Pt}(\text{NH}_3)_2\text{Cl}_2$. Give reasons for your answer.

(a(iii))[1]

Explain why oxaloplatin has no isomers.

(b(i))[1]

What does this suggest about the stereochemistry around the nickel atom?

(b(ii))[1]

Draw a three-dimensional diagram showing the structure of this complex.

Worked solution & mark scheme

This 6-mark question has a full step-by-step worked solution and mark scheme. One marking point: Both correct cis and trans isomers shown

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