Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

Lactic acid, $\text{CH}_3\text{CH(OH)COOH}$, is the sole monomer required to make the polymer polylactic acid, PLA.
(a(i))[2]

Draw a short length of the PLA polymer chain with at least two monomer residues included. The methyl groups may be written as $-\text{CH}_3$, but all the other bonds should be shown in full display. Label one repeat unit of polylactic acid on your diagram.

(a(ii))[1]

State the type of polymerisation involved in producing PLA and the functional group formed between the monomers. type of polymerisation .............................................................. functional group ..............................................................

(a(iii))[1]

Predict whether PLA is readily biodegradable. Explain your answer.

(b(i))[3]

Use Fig. 8.1 together with Table 8.1 to complete Table 8.2.

(b(ii))[1]

Name the substance that gives the peak at $\delta = 0.0$.

(b(iii))[1]

Explain why $\text{CDCl}_3$ is a more suitable solvent than $\text{CHCl}_3$ for proton NMR.

(c(i))[1]

Explain what retention time means.

(c(ii))[1]

Suggest suitable substances, or types of substances, that could be used for the mobile and stationary phases. mobile phase .............................................................. stationary phase ..............................................................

(c(iii))[1]

Describe how the percentage composition of the mixture can be worked out from the gas/liquid chromatogram.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: Polyester repeat unit shown with ester linkage and continuation bonds

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