Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

(a)[1]

The table presents three monomer pairs that can polymerise. Complete the table by naming the polymerisation type for each pair.

(b(i))[3]

$2$-aminopropanoic acid, $\text{CH}_3\text{CH(NH}_2)\text{CO}_2\text{H}$, is able to polymerise under suitable conditions. No other monomer takes part in this reaction. Draw a section of the polymer chain produced, including $\mathbf{three}$ monomer residues. Clearly indicate $\mathbf{one}$ repeat unit on your diagram.

(b(ii))[2]

$2$-aminopropanoic acid, $\text{CH}_3\text{CH(NH}_2)\text{CO}_2\text{H}$, occurs as two stereoisomers. Draw three-dimensional diagrams to illustrate the two stereoisomers of $2$-aminopropanoic acid. State the type of stereoisomerism shown.

(c(i))[1]

The skeletal formula for compound $W$ is shown. When $W$ is combined with a second compound, known as a hardener, polymerisation takes place and a non-solvent-based adhesive is formed. Give the name of this type of non-solvent-based adhesive.

(c(ii))[1]

The hardener is a diamine. A diamine contains an alkyl chain with two amine groups that are not attached to the same carbon atom. Draw the structural formula of a compound that could act as a suitable hardener.

Worked solution & mark scheme

This 8-mark question has a full step-by-step worked solution and mark scheme. One marking point: monomer pairs and polymerisation types correctly matched

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