Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

(a(i))[2]

Polyhydroxyamide is a fire-resistant polyamide formed from the two monomers, F and G. Predict how many peaks will appear in the carbon-13 NMR spectra of F and G.

(a(ii))[2]

Draw the repeat unit of polyhydroxyamide. The amide bond must be displayed.

(b)[2]

When poly(ethene) is made from ethene, several bonds are broken and formed. Put one tick (✓) in each row of the table to show the types of bonds broken and formed in this process.

(c)[2]

Addition polymers can be sorted into two categories: homopolymer - a polymer made from the same monomer unit; copolymer - a polymer made from two or more different monomer units. The reaction of propene, $\text{CH}_3\text{CH}=\text{CH}_2$, with phenylethene, $\text{C}_6\text{H}_5\text{CH}=\text{CH}_2$, produces a copolymer. Draw a section of this copolymer chain that contains one molecule of each monomer.

(d(i))[1]

Polyalkenes biodegrade very slowly. Explain why, with reference to the structures of the polymers.

(d(ii))[2]

Some polymers break down in the environment. Describe two processes by which this happens.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: Peak number is correct: F = 3, G = 6

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