Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

(a)[1]

Polymers may be produced by addition polymerisation or condensation polymerisation. Complete the table to indicate the polymerisation method for nylon, PVC (polychloroethene) and *Terylene*.

(b)[2]

*Nomex* is a polymeric material with excellent flame-resistant properties. It is made from a polymer formed from the two monomers shown. Draw the polymer structure with two repeat units, and show the links between monomer units in full displayed form.

(c)[1]

Proteins are natural polymers. Explain what the term primary structure of a protein means.

(d)[2]

Use the diagram to illustrate one way in which the $\alpha$-helix secondary structure in proteins is stabilised.

(e(i))[1]

The tertiary structure of a protein is destroyed during the process of denaturation. Explain how the addition of alkali can cause this.

(e(ii))[1]

The tertiary structure of a protein is destroyed during the process of denaturation. Explain how the addition of $\text{Hg}^{2+}$ ions can cause this.

(e(iii))[1]

The tertiary structure of a protein is destroyed during the process of denaturation. Explain how heating to $70\ ^\circ\text{C}$ can cause this.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: Nylon and terylene: condensation polymerisation; PVC: addition polymerisation

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