Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

Rising concern over the shrinking availability of crude oil has led to several efforts to substitute oil-based polymers with polymers obtained from natural raw materials. One example is ‘polylactide’ or PLA, which is made from corn starch and has many uses.
(a(i))[1]

Calcium hydroxide is put into the fermentation tanks so that the production of lactic acid does not slow down. Why might high acidity reduce the effectiveness of the enzymes?

(a(ii))[2]

The structure of lactic acid is shown. What type of reaction occurs in this polymerisation?

(b)[1]

Lactic acid has two stereoisomeric forms. Draw the other form in the box.

(c(i))

Explain why PLA would not be a suitable packaging material for foods preserved in vinegar.

(c(ii))[2]

PLA containers are not used for hot drinks. Suggest why.

(d(i))

Draw a section of the co-polymer that shows one repeat unit.

(d(ii))

Suggest what type(s) of bonding will act between chains of this co-polymer, indicating the groups involved.

(d(iii))

Suggest one property in which the co-polymer is different from PLA.

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