Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

1,3-dimethylbenzene is a valuable starting material for several compounds of commercial importance.
(a(i))[1]

In step 2, the only by-product is $\text{HCl}$. Identify the reagent that was used in this step.

(a(ii))[1]

Suggest the reaction type occurring in both step 2 and step 3.

(a(iii))[1]

State the reagents and conditions required for step 3.

(a(iv))[2]

Suggest the structures of the two products formed when A reacts with alkaline aqueous iodine.

(b(i))[1]

Draw one repeat unit structure of Nomex in the box above.

(b(ii))[1]

What type of polymer does Nomex belong to?

(b(iii))[1]

Suggest the by-product produced during step 3.

(b(iv))[1]

Suggest reagents and conditions for step 2.

(b(v))[1]

Suggest how and why the properties of the polymer might change if some of the diamine monomer were replaced with 1,3,5-triaminobenzene.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: ethanoyl chloride or $\mathrm{CH_3COCl}$

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