Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

A number of widely used polymers are produced through the polymerisation of ethene, $\text{C}_2\text{H}_4$. Side-chains alter the bulk properties of an addition polymer. Polymers with no branches pack more closely than polymers with several side-chains.
(a)[2]

Using sketches, Explain why side-chains cause a difference in density in poly(ethene).

(b)[2]

Using the type of bonding between the poly(ethene) chains, explain why LDPE has a lower melting point than HDPE.

(c)[2]

Polymerisation may occur by two different methods, depending on the monomers used. These methods are addition and condensation. Give two differences between them.

(d(i))

Suggest the way in which this polymer conducts electricity.

(d(ii))

Suggest the molecular geometry needed for this molecule to conduct. Explain your answer.

(d(iii))

State the empirical formula of this polymer.

Worked solution & mark scheme

This 6-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate sketches of LDPE (branched) and HDPE (unbranched)

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