Chemistry 9701 · AS & A Level · Polymerisation

Polymerisation — practice question

Some of the polymers most often used are made by polymerising ethene, $\text{C}_2\text{H}_4$. Side-chains change the bulk properties of an addition polymer. Polymers with no branches can pack more tightly than those with many side-chains.
(a)[2]

Explain, using sketches, why side-chains lead to a density difference in poly(ethene).

(b)[2]

By referring to the type of bonding between the poly(ethene) chains, explain why LDPE melts at a lower temperature than HDPE.

(c)[2]

Polymerisation can happen by two distinct methods, depending on the monomers involved. These methods are addition and condensation. Give two differences between the methods.

(d(i))

Suggest the way in which this polymer conducts electricity.

(d(ii))

Suggest the molecular geometry needed for this molecule to conduct. Explain your answer.

(d(iii))

What is the empirical formula for this polymer?

Worked solution & mark scheme

This 6-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accurate sketches of LDPE and HDPE chains (min. 2)

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