Chemistry 9701 · AS & A Level · Nitrogen and sulfur

Nitrogen and sulfur — practice question

(a(i))[2]

Explain why nitrogen gas, $\text{N}_2(g)$, is not very reactive.

(a(ii))[4]

Covalent bonds may be $\sigma$ bonds or $\pi$ bonds. Complete Table 1.1 to show how many $\sigma$ and $\pi$ bonds are present in a molecule of $\text{N}_2$, and to describe the orbital overlap that forms $\sigma$ and $\pi$ bonds.

(b(i))[1]

A sample of $\text{Al}$ is reacted with excess $\text{Cl}_2$. State the oxidation number of $\text{Al}$ in the product formed.

(b(ii))[1]

State what determines the highest oxidation number of the Period 3 elements in their oxides.

(c(i))[1]

Separate samples of aluminium oxide, $\text{Al}_2\text{O}_3$, and phosphorus(V) oxide, $\text{P}_4\text{O}_{10}$, are each reacted with excess $\text{NaOH}(aq)$ at room temperature. Give the state of $\text{Al}_2\text{O}_3$ and $\text{P}_4\text{O}_{10}$ at room temperature.

(c(ii))[2]

Write an equation for the reaction of each oxide with excess $\text{NaOH}(aq)$ at room temperature.

(d(i))[1]

The oxide of silicon reacts with calcium oxide in an addition reaction to make calcium silicate, $\text{CaSiO}_3$. The oxidation number of calcium in $\text{CaSiO}_3$ is $+\text{II}$. Deduce the oxidation number of silicon in calcium silicate.

(d(ii))[1]

Calcium oxide can be obtained from calcium carbonate in a single-step reaction. Identify the type of reaction that takes place.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: Each $\mathrm{N_2}$ molecule has a strong triple (covalent) bond

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