Chemistry 9701 · AS & A Level · Nitrogen and sulfur

Nitrogen and sulfur — practice question

At room temperature, sulfur chloride, $\text{SCl}_2$, is a liquid. If $\text{SCl}_2$ is added to water, mist-like fumes appear and a solution is formed that makes universal indicator red.
(a(i))[1]

Identify the type of reaction when $\text{SCl}_2$ is introduced into water.

(a(ii))[1]

Name a chloride of another Period 3 element that is also a liquid at room temperature and forms misty fumes when water is added.

(b(i))[2]

Complete the dot-and-cross diagram in Fig. 2.1 so that it shows the outer-electron arrangement in a molecule of $\text{SCl}_2$. Use $\times$ for electrons from the chlorine atoms. Use $\bullet$ for electrons from the sulfur atom.

(b(ii))[2]

Predict the shape of, and bond angle in, a molecule of $\text{SCl}_2$ using VSEPR theory.

(c(i))[1]

Deduce the oxidation numbers of magnesium and nitrogen in magnesium nitride, $\text{Mg}_3\text{N}_2$, to finish Table 2.1.

(c(ii))[1]

Magnesium nitride reacts with excess water to form only ammonia and magnesium hydroxide. Construct an equation for this reaction.

(c(iii))[2]

Explain why the solution formed in the reaction in (c)(ii) has a pH above 7. Refer to the products of the reaction in your answer.

(d(i))[1]

Use Fig. 2.2 to deduce the empirical formula of boron nitride.

(d(ii))[1]

Suggest the identity of another crystalline solid whose atoms are arranged in layers like those in solid boron nitride.

Worked solution & mark scheme

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