Chemistry 9701 · AS & A Level · Nitrogen and sulfur

Nitrogen and sulfur — practice question

Nitric acid, $\text{HNO}_3$, is produced by reacting nitrogen dioxide with water. The reaction enthalpy change may be determined indirectly by means of a Hess’ cycle. $3\text{NO}_2(\text{g}) + \text{H}_2\text{O}(\ell) \xrightarrow{\Delta H_r} 2\text{HNO}_3(\ell) + \text{NO}(\text{g})$
(a)[2]

Explain the meaning of the term enthalpy change of formation.

(b)[3]

Using the values in the table, finish the Hess’ cycle and therefore calculate the enthalpy change, $\Delta H_r$, for this reaction. Show your working.

(c)[2]

Explain why nitrogen and oxygen fail to react at normal atmospheric temperatures.

(d)[1]

State one natural route by which nitrogen oxides are produced.

(e(i))[3]

Explain why $\text{NO}_2$ is described as a homogeneous catalyst in the oxidation of atmospheric sulfur dioxide.

(e(ii))[2]

Write equations that show the two reactions taking place when $\text{NO}_2$ acts as a catalyst in the formation of sulfur trioxide from sulfur dioxide.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: The enthalpy / energy change that occurs when one mole of a compound is formed

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI