Chemistry 9701 · AS & A Level · Nitrogen and sulfur

Nitrogen and sulfur — practice question

The release of sulfur dioxide, $\text{SO}_2$, into the atmosphere leads to acid rain.
(a)[2]

Explain why the atmosphere near power stations that burn fossil fuels may contain high concentrations of $\text{SO}_2$.

(b(i))[2]

The $\text{SO}_2$ released can be turned in the atmosphere into sulfuric acid, $\text{H}_2\text{SO}_4$, through reaction with nitrogen dioxide gas, $\text{NO}_2$, and water, $\text{H}_2\text{O}$. The reactions are: $\text{SO}_2 + \text{NO}_2 \rightarrow \text{NO} + \text{SO}_3$ $\text{SO}_3 + \text{H}_2\text{O} \rightarrow \text{H}_2\text{SO}_4$ In one year, a fossil-fuel power station emitted 1590 tonnes of $\text{SO}_2$ into the atmosphere. Use the equations to work out how many tonnes of $\text{H}_2\text{SO}_4$ were produced in the atmosphere. Assume that every bit of the $\text{SO}_2$ released was changed into $\text{H}_2\text{SO}_4$.

(b(ii))[2]

Describe how $\text{NO}_2$ is also formed by these power stations.

(b(iii))[1]

State one natural cause of $\text{NO}_2$ forming in the atmosphere.

(b(iv))[2]

Explain why $\text{NO}_2$ may be described as a catalyst in the oxidation of atmospheric $\text{SO}_2$.

Worked solution & mark scheme

This 9-mark question has a full step-by-step worked solution and mark scheme. One marking point: Sulfur impurities OR sulfur contained in fossil fuels

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