Chemistry 9701 · AS & A Level · Hydrocarbons

Hydrocarbons — practice question

(a)[1]

Define what is meant by mole.

(b)

10 cm$^3$ of a gaseous hydrocarbon, $\mathrm{C}_x\mathrm{H}_y$, was mixed with 100 cm$^3$ of oxygen gas, in excess. The gas mixture had a final volume of 95 cm$^3$. Concentrated, aqueous sodium hydroxide was then used on the mixture to absorb the carbon dioxide present. The gas volume then fell to 75 cm$^3$. Every gas volume was measured at 298 K and 100 kPa.

(b(i))[1]

Write an equation for the reaction of sodium hydroxide with carbon dioxide.

(b(ii))[1]

Calculate the carbon dioxide volume produced by combustion of the hydrocarbon.

(b(iii))[1]

Calculate the volume of oxygen consumed in the reaction with the hydrocarbon.

(b(iv))[2]

Use your answers to (b)(ii) and (b)(iii), together with the initial hydrocarbon volume, to balance the equation below: $\mathrm{C}_x\mathrm{H}_y + \dots \mathrm{O}_2 \rightarrow \dots \mathrm{CO}_2 + z\mathrm{H}_2\mathrm{O}$.

(b(v))[3]

Deduce the values of $x$, $y$ and $z$ in the equation in (iv).

(c)

Another hydrocarbon, $W$, with the formula $\mathrm{C}_4\mathrm{H}_8$, reacts with hydrogen bromide, HBr, to give two products $X$ and $Y$. $X$ and $Y$ are structural isomers of molecular formula $\mathrm{C}_4\mathrm{H}_9\mathrm{Br}$. Reaction of $X$ with aqueous alkali produces an alcohol, $Z$, that has no reaction with acidified dichromate(VI).

(c(i))[4]

Give the structures and names of compounds $W$, $X$, $Y$ and $Z$.

(c(ii))[2]

When $W$ reacts with hydrogen bromide, more $X$ than $Y$ is formed. Explain why.

Worked solution & mark scheme

This 15-mark question has a full step-by-step worked solution and mark scheme. One marking point: The amount of substance that contains $6.02 \times 10^{23}$ (fundamental) particles of the substance, or the amount of substance containing the same number of particles as there are atoms in $12\,\text{g}$ of carbon-12

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