Chemistry 9701 · AS & A Level · Halogen compounds

Halogen compounds — practice question

Trihalomethanes are organic compounds in which three hydrogen atoms in methane have been replaced by halogen atoms, such as $\text{CHCl}_3$.
(a(i))[2]

$\text{CHCl}_3$ is a colourless liquid with a high vapour pressure. Explain what is meant by the term high vapour pressure.

(a(ii))[3]

A significant reaction of $\text{CHCl}_3(g)$ is the production of $\text{CHClF}_2(g)$ by means of the reversible reaction: $\text{CHCl}_3(g) + 2\text{HF}(g) \rightleftharpoons \text{CHClF}_2(g) + 2\text{HCl}(g)$ Use the data to work out the enthalpy change of reaction, $\Delta H_r$, for forming $\text{CHClF}_2(g)$ as shown in the equation.

(a(iii))[3]

The reaction in (ii) uses a heterogeneous catalyst. Explain fully what is meant by the terms heterogeneous and catalyst.

(b(i))[1]

$\text{CHClF}_2$ was used in place of chlorofluorocarbons (CFCs). $\text{CHClF}_2$ should no longer be used because it was found to contribute to the enhanced greenhouse effect. Give the meaning of the term enhanced greenhouse effect.

(b(ii))[2]

Explain how $\text{CHClF}_2(g)$ may contribute to this effect.

(b(iii))[1]

Suggest another environmental problem associated with the use of $\text{CHClF}_2$.

(c(i))[1]

$\text{CHClF}_2$ is also used to make the monomer tetrafluoroethene, $\text{C}_2\text{F}_4$. This monomer can be used to make poly(tetrafluoroethene), PTFE. State the type of polymerisation that occurs during the production of PTFE.

(c(ii))[1]

Draw the repeat unit of PTFE.

(c(iii))[1]

Suggest why PTFE is used as a coating for cooking pans.

(c(iv))[2]

Waste disposal can create litter issues. State two other difficulties associated with the disposal of PTFE.

Worked solution & mark scheme

This 17-mark question has a full step-by-step worked solution and mark scheme. One marking point: Gas or vapour in equilibrium with a liquid or solid

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