Chemistry 9701 · AS & A Level · Group 2

Group 2 — practice question

The elements in Group 14 change from non-metallic to metallic in character as you go down the group.
(a(i))[3]

Complete Table 3.1 by filling in the missing entries.

(a(ii))[1]

Identify the lattice type shown by graphite.

(a(iii))[1]

Explain why Sn conducts electricity well.

(b(i))[1]

Write an equation for the reaction between magnesium carbonate and dilute $\text{HCl(aq)}$.

(b(ii))[1]

Describe how the thermal stability of the carbonates changes down Group 2.

(b(iii))[2]

Ammonium carbonate takes part in an acid-base reaction with $\text{NaOH(aq)}$.\n\nExplain this statement.

(c(i))[2]

Complete the graph in Fig. 3.1 so that it shows the third to sixth ionisation energies of Si.

(c(ii))[1]

Construct an equation that represents the second ionisation energy of Si.

(d(i))[2]

Explain the pattern in the boiling points of the Group 14 hydrides shown in Fig. 3.2.

(d(ii))[1]

Deduce the shape of a molecule of $\text{SiH}_4$.

(e(i))[1]

Write an equation showing how $\text{SiCl}_4$ is formed from its constituent elements.

(e(ii))[1]

Describe what you observe when a small amount of $\text{SiCl}_4$ is added to water.

(e(iii))[2]

$\text{SiO}_2$ is a white solid that melts above $1700^\u0016\text{C}$. $\text{SiCl}_4$ is a colourless liquid at room temperature. Explain why these two compounds have different melting points with reference to structure and bonding.

(f)[1]

Tin forms an amphoteric oxide, $\text{SnO}_2$. Suggest the formula of the tin compound formed when $\text{SnO}_2$ reacts with $\text{H}_2\text{SO}_4$ in an acid-base reaction.

Worked solution & mark scheme

This 20-mark question has a full step-by-step worked solution and mark scheme. One marking point: A correct comparison of C (graphite) and Sn in terms of appearance, conductivity, bonding and structure

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