Chemistry 9701 · AS & A Level · Group 2

Group 2 — practice question

Magnesium silicide, $Mg_2Si$, is a compound formed by heating magnesium with sand.
(a)[2]

Draw a ‘dot-and-cross’ diagram to show how the outer electrons are arranged in one formula unit of $Mg_2Si$. Assume that magnesium silicide is ionic.

(b)[2]

When solid $Mg_2Si$ is added to water, silane gas, $SiH_4$, and a solution of magnesium hydroxide are formed. Write the equation for this reaction. Include state symbols.

(c)[2]

Suggest, with reference to structure and bonding, why $SiH_4$ exists as a gas at room temperature.

(d(i))[2]

The table gives the electronegativity values of carbon, hydrogen and silicon. $C$-$H$ and $Si$-$H$ bonds have weak dipoles. Use the electronegativity values in the table to show the polarity of the $C$-$H$ and $Si$-$H$ bonds.

(d(ii))[2]

Explain why methane, $\text{CH}_4$, does not have an overall dipole moment.

(e)[2]

$\text{SiH}_4 + 2\text{O}_2 \rightarrow \text{SiO}_2 + 2\text{H}_2\text{O}$ $\text{CH}_4 + 2\text{O}_2 \rightarrow \text{CO}_2 + 2\text{H}_2\text{O}$ Suggest, with reference to bond energies from the Data Booklet, why $\text{SiH}_4$ reacts in air without heating but $\text{CH}_4$ has to be ignited before combustion occurs.

(f(i))[2]

Silicon dioxide reacts with hot, concentrated sodium hydroxide. Identify the two products formed in this reaction.

(f(ii))[1]

Describe how the silicon dioxide behaves during this reaction.

Worked solution & mark scheme

This 15-mark question has a full step-by-step worked solution and mark scheme. One marking point: magnesium indicated as $2+$ on two Mg ions, with 0 or 8 outer electrons

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