Chemistry 9701 · AS & A Level · Group 2

Group 2 — practice question

Group 2 elements have similar chemical properties.
(a(i))[2]

Calcium reacts with cold water more rapidly than magnesium because more energy is needed to remove the outer electrons in magnesium. This is true even though calcium atoms have a greater nuclear charge. Explain why more energy is required to remove the outer electrons in magnesium than in calcium.

(a(ii))[2]

$0.001\,\text{mol}$ of strontium is reacted with an excess of cold water. Once the reaction is complete, a colourless solution is seen. Construct the equation for the reaction of strontium with cold water. Include state symbols.

(a(iii))[2]

$0.005\,\text{mol}$ of calcium and $0.005\,\text{mol}$ of strontium are added separately to two beakers. Each beaker contains $100\,\text{cm}^3$ of cold water. At the end of both reactions, a white solid and a colourless solution are observed in both beakers. Predict which element, calcium or strontium, produces the more alkaline solution. Explain your answer.

(a(iv))[1]

Describe one observation that occurs when magnesium carbonate is added to excess dilute sulfuric acid.

(b(i))[3]

Element $X$ is a metal. $X$ reacts with oxygen to make a black solid oxide. In this oxide, the oxidation state of $X$ is $+2$. The carbonate of $X$, $XCO_3$, is a green solid. On heating, it decomposes to the oxide and a colourless gas. Using the information given, state two similarities and one difference between metal $X$ and its compounds and Group 2 metals and their compounds.

(b(ii))[1]

Write the formula for the oxide of $X$.

(b(iii))[1]

Write an equation for the reaction of $XCO_3$ on heating.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: fewer (inner) shells of electrons / reduced shielding effect

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