Chemistry 9701 · AS & A Level · Group 2

Group 2 — practice question

The table below gives the solubilities of the hydroxides and carbonates of several Group 2 elements, M, at $25\,^{\circ}\text{C}$.
(a(i))[3]

Explain why the solubility of the Group 2 hydroxides, $\text{M(OH)}_2$, rises down the group.

(a(ii))[1]

Suggest a reason for the general decrease in the solubility of the Group 2 carbonates, $\text{MCO}_3$, down the group.

(a(iii))[2]

When carbon dioxide is bubbled through a saturated solution of calcium hydroxide (limewater), a white precipitate of calcium carbonate forms. Use the data in the table to decide, for each of Mg, Sr and Ba, whether a saturated solution of its hydroxide could also be used to test for carbon dioxide. Justify your answer. No calculations are needed.

(b(i))[2]

Calculate the value of the solubility product, $K_{sp}$, of magnesium hydroxide at $25\,^{\circ}\text{C}$.

(b(ii))[2]

State what would be observed if a few drops of a saturated solution of barium hydroxide are added to a saturated solution of barium carbonate. Explain your answer.

(c)[3]

The equation for forming the gaseous hydroxide ion is given as $\tfrac{1}{2}\text{H}_2\text{(g)} + \tfrac{1}{2}\text{O}_2\text{(g)} + e^- \rightarrow \text{OH}^-\text{(g)}$, $\Delta H = \Delta H_f^\theta(\text{OH}^-\text{(g)})$. Use the data in the table and from the Data Booklet to calculate $\Delta H_f^\theta(\text{OH}^-\text{(g)})$. You may find it helpful to construct a Born-Haber cycle.

Worked solution & mark scheme

This 13-mark question has a full step-by-step worked solution and mark scheme. One marking point: The values of $\Delta H_{\text{latt}}$ and $\Delta H_{\text{hyd}}$ both get smaller

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