Chemistry 9701 · AS & A Level · Group 17

Group 17 — practice question

(a(i))[1]

In the laboratory, hydrogen chloride gas is produced by adding concentrated sulfuric acid to potassium chloride. Write an equation for this reaction.

(a(ii))[2]

Explain why hydrogen iodide is not made by adding concentrated sulfuric acid to sodium iodide.

(b(i))[1]

A sample of $\\text{HI(g)}$ is placed in a sealed $2.00\\,\\text{dm}^3$ vessel at $764\\,\\text{K}$ and left until equilibrium is reached.\n\nReaction 1:\n$2\\text{HI(g)} \\rightleftharpoons \\text{H}_2\\text{(g)} + \\text{I}_2\\text{(g)}$ with $K_c = 0.0217$ at $764\\,\\text{K}$.\n\nAt equilibrium the mixture contains $1.70\\,\\text{mol}$ of $\\text{HI(g)}$.\n\nState one difference in appearance between the initial mixture and the mixture at equilibrium.

(b(ii))[1]

Deduce the equilibrium constant expression $K_c$ for reaction 1.\n\n$K_c =$

(b(iii))[3]

Calculate the concentration of $\\text{I}_2$ in the equilibrium mixture. Show your working.

(c(i))[1]

The experiment is carried out again at $500\\,\\text{K}$. Under these conditions, $K_c$ is $0.00625$. Describe how the composition of the equilibrium mixture at $500\\,\\text{K}$ differs from that at $764\\,\\text{K}$.

(c(ii))[1]

Use Le Chatelier’s principle to decide whether the decomposition of $\\text{HI(g)}$ is endothermic or exothermic. Explain your answer.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: Accept either $\\mathrm{2KCl + H_2SO_4 \\rightarrow K_2SO_4 + 2HCl}$ or $\\mathrm{KCl + H_2SO_4 \\rightarrow KHSO_4 + HCl}$.

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