Chemistry 9701 · AS & A Level · Group 17

Group 17 — practice question

The Group 17 elements chlorine, bromine and iodine are non-metals, and their physical and chemical properties follow clear trends.
(a)[1]

Describe how the colour of the Group 17 elements changes as you go down the group.

(b(i))[1]

Describe how the relative reactivity of the elements in Group 17 as oxidising agents changes.

(b(ii))[2]

Chlorine reacts with hot tin metal to make tin(IV) chloride, $\text{SnCl}_4$. $\text{SnCl}_4$ is a colourless liquid at room temperature and reacts vigorously with water to give an acidic solution. Suggest the structure and bonding in $\text{SnCl}_4$. Explain your answer.

(c(i))[2]

Describe the observations when dilute $\text{AgNO}_3(aq)$ is added to $\text{NaBr}(aq)$ and then aqueous ammonia is added.

(c(ii))[3]

$\text{NaCl}$ reacts with concentrated $\text{H}_2\text{SO}_4$ to give $\text{HCl}$ and $\text{NaHSO}_4$. Explain why the reactions of concentrated $\text{H}_2\text{SO}_4$ with $\text{NaCl}$ and with $\text{NaI}$ are different. Your response should refer to the role of the sulfuric acid in each case.

(d(i))[2]

Describe and explain the pattern in the boiling points of the hydrogen halides, $\text{HCl}$, $\text{HBr}$ and $\text{HI}$.

(d(ii))[2]

Describe and explain the pattern in the thermal stabilities of the hydrogen halides, $\text{HCl}$, $\text{HBr}$ and $\text{HI}$.

(e(i))[1]

Explain the meaning of the term homogeneous.

(e(ii))[1]

Pentan-3-ol, $\text{C}_2\text{H}_5\text{CH(OH)}\text{C}_2\text{H}_5$, reacts slowly with $\text{HCl}$ to produce a secondary halogenoalkane. Complete the reaction equation using structural formulae: $\text{C}_2\text{H}_5\text{CH(OH)}\text{C}_2\text{H}_5 + ...

(e(iii))[1]

Draw the structure of the tertiary alcohol that is an isomer of pentan-3-ol.

(e(iv))[1]

Suggest the type of reaction shown by tertiary alcohols with Lucas’s reagent.

Worked solution & mark scheme

This 17-mark question has a full step-by-step worked solution and mark scheme. One marking point: darker / more intense / deeper as you go down the group

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