Chemistry 9701 · AS & A Level · Equilibria

Equilibria — practice question

These circuits were assembled with aqueous hydrochloric acid and aqueous ethanoic acid as the electrolytes. Assume that, apart from the electrolyte, the two circuits were the same.
(a)[2]

Once the switches had been closed, bulb 1 gave a brighter light than bulb 2. Explain why.

(b(i))

State what is meant by a buffer solution.

(b(ii))[4]

Outline how a buffer solution may be prepared from ethanoic acid and a named base.

(c)[2]

Amino acids such as alanine, $\text{CH}_3\text{CH(NH}_2\text{)CO}_2\text{H}$, may act as a buffer solution. Write two equations to demonstrate this.

(d(i))

Tartaric acid has two dissociation constants, $K_1$ and $K_2$, with $\text{p}K_a$ values of 2.99 and 4.40. Suggest equations for the two dissociations that produce these $\text{p}K_a$ values.

(d(ii))[4]

One stereoisomer of tartaric acid is displayed. Complete the diagrams to show two other stereoisomers of tartaric acid.

Worked solution & mark scheme

This 12-mark question has a full step-by-step worked solution and mark scheme. One marking point: Greater dissociation of $\text{HCl}$ / stronger acid

  • Full mark scheme, point by point
  • Step-by-step worked solution
  • Write your answer & get it marked instantly by AI