Chemistry 9701 · AS & A Level · Equilibria

Equilibria — practice question

Sodium oxide, $\text{Na}_2\text{O}$, is a white, crystalline solid that melts at a high temperature.
(a)[2]

Write an equation for sodium's reaction with oxygen to form sodium oxide. Include state symbols.

(b)[2]

Explain why the melting point of sodium oxide is high.

(c(i))[2]

When sodium oxide reacts with water, an alkaline solution forms. Explain why this solution is alkaline. In your answer, use the Brønsted-Lowry theory of acids and bases.

(c(ii))[3]

Calculate the pH of the solution formed when $3.10\,\text{g}$ of sodium oxide is added to $400\,\text{cm}^3$ of water.

(d)[4]

Using the data below, together with any other suitable values from the Data Booklet, calculate the lattice energy of sodium oxide, $\Delta H^{\circ}_{\text{latt}}\ \text{Na}_2\text{O(s)}$.

(e)[2]

State the way in which $\Delta H^{\circ}_{\text{latt}}\ \text{Na}_2\text{S(s)}$ differs from $\Delta H^{\circ}_{\text{latt}}\ \text{Na}_2\text{O(s)}$. Show this by putting a tick ($\checkmark$) in the correct box in the table. Explain your answer.

Worked solution & mark scheme

This 15-mark question has a full step-by-step worked solution and mark scheme. One marking point: Correct balanced equation $4Na(s) + O_2(g) \rightarrow 2Na_2O(s)$ using the right formulae

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