Chemistry 9701 · AS & A Level · Equilibria

Equilibria — practice question

The water in a swimming pool can be kept free from harmful bacteria by adding aqueous sodium chlorate(I), $\text{NaOCl}$. This then reacts with water to form $\text{HOCl}$ molecules that kill bacteria. $\text{OCl}^-(aq) + \text{H}_2\text{O} \rightleftharpoons \text{OH}^-(aq) + \text{HOCl}(aq)$ Under strong sunlight, the $\text{OCl}^-$ ion is decomposed by ultra-violet light. $\text{OCl}^-(aq) + \text{UV light} \rightarrow \text{Cl}^-(aq) + \tfrac{1}{2}\text{O}_2(g)$ Which method would keep the concentration of $\text{HOCl}(aq)$ at the highest level?

  • Aacidify the pool water
  • Badd a solution of chloride ions
  • Cadd a solution of hydroxide ions
  • Dbubble air through the water

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