Chemistry 9701 · AS & A Level · Electrochemistry

Electrochemistry — practice question

Use data from Table 3.1 to answer some parts of this question.
(a(i))[2]

Define standard electrode potential. Include the standard conditions used.

(a(ii))[3]

Complete the diagram below to show an electrochemical cell made from a $\text{Mg}^{2+}/\text{Mg}$ half-cell and a $\text{MnO}_4^-/\text{Mn}^{2+}$ half-cell. Add labels to your diagram.

(a(iii))[1]

Use a positive $(+)$ sign and a negative $(-)$ sign to show the polarity of each electrode in your diagram. Add an arrow together with the symbol $e^-$ to indicate the direction of electron flow in the external circuit.

(a(iv))[1]

Calculate the standard cell potential, $E^\circ_{\text{cell}}$, for this cell.

(a(v))[1]

Construct an equation for the cell reaction.

(a(vi))[1]

Predict how the cell reaction will change, if at all, when the solution in the $\text{Mg}^{2+}/\text{Mg}$ half-cell is diluted by the addition of a large volume of water. Explain your answer.

(b)[2]

A molten magnesium salt is electrolysed for $15.0$ minutes by a constant current. $4.75 \times 10^{22}$ magnesium atoms are formed at the cathode. Calculate the current used.

Worked solution & mark scheme

This 11-mark question has a full step-by-step worked solution and mark scheme. One marking point: Voltage given by a half-cell when measured against a standard hydrogen electrode

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