Chemistry 9701 · AS & A Level · Electrochemistry

Electrochemistry — practice question

An excess amount of sodium iodide is added to a copper(II) sulfate solution. Iodine is produced together with a white precipitate of copper(I) iodide.
(a)[1]

State an equation for the reaction that takes place.

(b(i))[4]

Explain why the copper(II) sulfate solution has a colour.

(b(ii))[1]

Suggest a reason why the copper(I) iodide precipitate is white.

(c)[2]

Use suitable $E^{\circ}$ values from the Data Booklet to decide whether iodide ions are able to reduce $\text{Cu}^{2+}$ to $\text{Cu}^+$ under standard conditions. Justify your answer.

(d)[2]

An excess of sodium iodide is added to copper(II) sulfate solution. Copper(I) iodide appears as a precipitate. After the precipitate forms, $[\text{Cu}^+]$ is much lower than $1.0\ \text{mol dm}^{-3}$. Use this and your answer to (c) to explain how the relevant electrode potentials change and therefore why $\text{I}^-$ ions can reduce $\text{Cu}^{2+}$ ions.

Worked solution & mark scheme

This 10-mark question has a full step-by-step worked solution and mark scheme. One marking point: $2\mathrm{Cu^{2+}} + 4\mathrm{I^-} \to 2\mathrm{CuI} + \mathrm{I_2}$

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